Spectra & Composition

What’s It Made Of, and How Is It Moving?

Dr. Anna Rosen

February 17, 2026

Learning Objectives

  • Explain Kirchhoff’s three laws and predict which spectrum a source produces
  • Interpret the Bohr model to explain why spectral lines have specific wavelengths
  • Classify stars by spectral type (OBAFGKM) as a temperature sequence
  • Apply the Doppler shift to measure stellar radial velocities
  • Connect spectral absorption to the greenhouse effect

All stars are \({\sim}73\%\) hydrogen and \({\sim}25\%\) helium.

So why do their spectra look so different?

Today’s Roadmap

  1. Kirchhoff’s Laws — why stars show absorption spectra
  2. Spectral Lines — atomic fingerprints from the Bohr model
  3. OBAFGKM — a temperature sequence, not composition
  4. Doppler Shift — reading stellar motion from light
  5. Putting It Together — three clues from one spectrum
  6. Climate Connection — same physics, different scale

Kirchhoff’s Laws

Three spectra, three physical setups

Three Types of Spectra

Diagram showing three scenarios: (1) continuous spectrum from hot dense object producing rainbow, (2) absorption spectrum with dark lines when cool gas absorbs from continuous source, (3) emission spectrum with bright lines from hot thin gas cloud.
Credit: JWST/STScI
  1. Continuous — hot, dense source → all wavelengths (Planck curve)
  2. Emission — hot, low-density gas → bright lines on dark background
  3. Absorption — cooler gas in front of hot continuum → dark lines

The same gas produces emission OR absorption depending on what’s behind it.

Quick Label (30 seconds)

For each spectrum type, write down: (1) the type and (2) the physical setup in six words or fewer.

Example format:

  • Continuous — hot, dense source emits all wavelengths.
  • Emission — hot, thin gas emits bright lines.
  • Absorption — cool gas blocks specific colors.

Kirchhoff’s Three Laws

  1. Hot, dense source → continuous spectrum (all wavelengths)
  2. Hot, low-density gas → emission lines (bright lines, dark background)
  3. Cooler gas in front of hot continuum → absorption lines (dark lines in rainbow)

The same gas absorbs at the same wavelengths it would emit.

The Reverse Problem

In practice, you work Kirchhoff’s laws backwards:

Given a spectrum → infer the physical configuration.

  • Dark lines in a rainbow? → cooler gas in front of a hotter continuum
  • Bright lines on dark background? → hot, tenuous gas, no continuum behind it
  • Smooth rainbow, no lines? → hot, dense source

This is the skill you’ll use for the rest of the course.

Why Stars Show Absorption Spectra

Cross-section of a stellar photosphere with curved layers labeled about 5800 K deeper and 4500 K higher up across roughly 500 km. Dashed sight lines from different depths connect to a spectrum panel showing a dark absorption line dip versus wavelength and intensity.
Credit: cococubed.com

Two-layer model:

  1. Photosphere (\(\tau \approx 1\)) — hot, dense → continuous spectrum (Law 1)
  2. Atmosphere (cooler, above) → absorbs at specific wavelengths (Law 3)

We see: a continuous rainbow with dark lines carved into it.

Temperature decreases outward — that’s why absorption, not emission.

Two Myths to Kill Now

Myth 1: “Spectral type tells me what a star is made of.”

It doesn’t — not directly. Spectral type primarily reflects temperature. Stars of wildly different types have nearly identical compositions. (Part 3 will prove this.)

Myth 2: “A redshifted star looks red.”

It doesn’t. “Redshift” means lines shift to longer wavelengths — a fractional change of \({\sim}0.01\%\). A blue O star receding from you is still blue. (Part 4 makes this quantitative.)

Observable → Model → Inference

  • Observable: Dark lines at specific wavelengths in a stellar spectrum
  • Model: Kirchhoff’s third law — cooler atmosphere absorbs from hotter photosphere
  • Inference: The star has a hot interior surrounded by a cooler atmosphere

The dark lines are the key to everything that follows.

🔍 Spectrum Detective — Clue 0: The shape of the spectrum (continuous vs. lines, absorption vs. emission) tells you the physical setup of the source.

Prediction: Which Spectrum?

You look at a glowing neon sign through a spectrograph.

Commit to one answer:

  1. Continuous spectrum — smooth rainbow

  2. Emission spectrum — bright lines on dark background

  3. Absorption spectrum — dark lines in a rainbow

Think–Pair–Share: Design a Kirchhoff Test

Scenario: You have a hydrogen gas tube and a bright white lamp.

  1. How would you set up an experiment to produce a hydrogen emission spectrum?
  2. How would you rearrange to produce a hydrogen absorption spectrum?
  3. Which Kirchhoff law governs each setup?

30 seconds alone → 1 minute with a neighbor → share out

Spectral Lines as Atomic Fingerprints

The Bohr model and discrete energy levels

The Bohr Model: Discrete Energy Levels

Left: Bohr model of hydrogen with electron energy levels 1-6. Right top: energy level diagram showing electron absorbing photons and jumping up. Right bottom: absorption spectrum with dark lines at specific wavelengths corresponding to transitions.
Credit: JWST/STScI

Electrons occupy specific energy rungs — they cannot hover between them.

The Reverse: Emission

Left: Bohr model of hydrogen with electron falling between levels. Right top: energy level diagram showing electron emitting photons while dropping down. Right bottom: emission spectrum with bright lines at specific wavelengths.
Credit: JWST/STScI

Same energy gaps → same wavelengths — whether absorbing or emitting.

Hydrogen Energy Levels

\[E_n = -\frac{13.6\ \text{eV}}{n^2}\]

  • \(n = 1\) (ground state): \(E_1 = -13.6\ \text{eV}\) — most tightly bound
  • \(n = 2\): \(E_2 = -3.4\ \text{eV}\)
  • \(n \to \infty\): \(E = 0\) — electron is free (ionized)

Negative sign = the electron is bound. You must add energy to free it.

Spectral Lines Come from Transitions

When an electron jumps between levels:

\[\Delta E = |E_{\text{upper}} - E_{\text{lower}}|\]

The photon’s wavelength is set by the energy gap:

\[\lambda = \frac{hc}{\Delta E}\]

Different elements → different energy levels → different spectral lines.

The Balmer Series: Hydrogen’s Visible Fingerprint

Transitions to/from \(n = 2\):

Transition Name Wavelength Color
\(n = 3 \to 2\) H\(\alpha\) \(656\ \text{nm}\) Deep red
\(n = 4 \to 2\) H\(\beta\) \(486\ \text{nm}\) Blue-green
\(n = 5 \to 2\) H\(\gamma\) \(434\ \text{nm}\) Violet
\(n = 6 \to 2\) H\(\delta\) \(410\ \text{nm}\) Near-UV

Energy gaps of \(\sim 1.9\text{–}3.0\ \text{eV}\) → visible wavelengths.

Worked Example: Calculating H\(\alpha\)

Problem: Predict the wavelength of \(n = 3 \to 2\) in hydrogen.

Step 1 — Energy levels: \[E_3 = \frac{-13.6\ \text{eV}}{9} = -1.51\ \text{eV} \qquad E_2 = \frac{-13.6\ \text{eV}}{4} = -3.40\ \text{eV}\]

Step 2 — Energy gap: \[\Delta E = |-1.51\ \text{eV} - (-3.40\ \text{eV})| = 1.89\ \text{eV}\]

Step 3 — CGS conversion: (\(1\ \text{eV} = 1.602 \times 10^{-12}\ \text{erg}\)) \[\lambda = \frac{hc}{\Delta E} = \frac{1.986 \times 10^{-16}\ \text{erg·cm}}{3.03 \times 10^{-12}\ \text{erg}} = 6.56 \times 10^{-5}\ \text{cm} = 656\ \text{nm}\ \checkmark\]

The \(hc\) Shortcut — Your Default Tool

For any transition with energy gap \(\Delta E\) (in eV):

\[\lambda\ (\text{nm}) \approx \frac{1240\ \text{eV·nm}}{\Delta E\ (\text{eV})}\]

For H\(\alpha\):

\[\lambda \approx \frac{1240\ \text{eV·nm}}{1.89\ \text{eV}} \approx 656\ \text{nm}\ \checkmark\]

Same answer, one line. Use \(hc \approx 1240\ \text{eV·nm}\) freely unless a problem asks for CGS.

Every Element Has a Unique Barcode

Absorption and emission spectra for sodium, nitrogen, hydrogen, and oxygen showing matching line patterns. Absorption spectra show dark lines on continuous rainbow; emission spectra show same-position bright lines on black background.
Credit: JWST/STScI

Match observed lines to laboratory wavelengths → identify the element.

🔍 Spectrum Detective — Clue 1: The positions of absorption lines tell you which elements are present — each element’s fingerprint is unique.

Real Data: Altair’s Spectrum

Top: rainbow spectrum image of star Altair showing dark absorption lines. Bottom: graph of brightness vs wavelength (about 400–700 nm) showing a smooth blackbody-like curve with sharp dips at absorption line wavelengths. Hydrogen Balmer lines labeled.
Credit: JWST/STScI

Two tools in one observation: the curve gives temperature (Wien), the lines give composition.

Think–Pair–Share: Mystery Element

A star’s spectrum shows absorption lines at \(393.4\ \text{nm}\) and \(396.8\ \text{nm}\) — but hydrogen has no transitions at these wavelengths.

  1. Are these lines from hydrogen? How do you know?
  2. These are the Ca II H & K lines (ionized calcium). What does “ionized” tell you about the temperature?
  3. In which spectral type(s) would you expect these lines to be strongest?

30 seconds alone → 1 minute with a neighbor → share out

Quick Check: Spectral Lines

An absorption line appears at \(486.1\ \text{nm}\) in a star’s spectrum. Which element and transition is this?

  • Helium, ground-state transition
  • Hydrogen, \(n = 4 \to 2\) (H\(\beta\))
  • Sodium, D-line transition
  • Iron, ionized state

OBAFGKM

A temperature sequence — not composition

The Harvard Computers

Black-and-white photograph from circa 1890 showing seven women working at desks in a room at Harvard College Observatory, examining photographic plates and notebooks. A light-curve chart labeled 'B Aurigae Dec 1889' hangs on the wall behind them.
Credit: Harvard College Observatory / Smithsonian Institution

500,000 glass plates. Millions of spectra. No automation.

  • Williamina Fleming — first classification system, 310 variable stars, Horsehead Nebula
  • Annie Jump Cannon — 350,000 spectra classified, OBAFGKM sequence
  • Antonia Maury — noticed line widths vary → luminosity class

Hired as cheap labor (25–50¢/hr, less than secretaries), denied telescope access — and they transformed astronomy.

Data First, Theory Later

The Harvard classifications demanded explanation:

  • 1925: Cecilia Payne-Gaposchkin proved stars are overwhelmingly hydrogen & helium — arguably the most important PhD in astronomy. Her advisor Russell called it “clearly impossible” before later admitting she was right.
  • 1920s: Eddington’s stellar models explained OBAFGKM as a temperature sequence.
  • 1938: Bethe’s nuclear fusion theory completed the picture.

The pattern was observed first. The physics was built to explain it.

This is Observable → Model → Inference in its purest historical form.

The Spectral Sequence

Composite image of stellar spectra arranged vertically from O6.5 at top to M5 at bottom, with wavelength increasing left to right across the visible band. Each horizontal strip shows a rainbow-colored spectrum with dark absorption lines at different positions. Star catalog identifiers (HD numbers) are labeled on the right. Three additional spectra at the bottom show an F4 metal-poor star, an M4.5 emission star, and a B1 emission star.
Credit: NOAO/AURA/NSF

From top to bottom: O → B → A → F → G → K → M

  • Hot (O): ionized helium lines
  • Middle (A): strongest hydrogen Balmer lines
  • Cool (M): molecular bands (TiO)

Spectral features change dramatically — but composition is nearly the same across all types.

Oh Be A Fine Guy/Girl, Kiss Me.

OBAFGKM at a Glance

Type Color Temperature Main-Seq. Prevalence Dominant Features
O Blue-violet \(\gtrsim 30{,}000\ \text{K}\) \(0.00003\%\) Ionized helium
B Blue-white \(10{,}000\text{–}30{,}000\ \text{K}\) \(0.13\%\) Neutral helium, strong H
A White \(7{,}500\text{–}10{,}000\ \text{K}\) \(0.6\%\) Strongest H Balmer
F Yellow-white \(6{,}000\text{–}7{,}500\ \text{K}\) \(3\%\) Moderate H, weak metals
G Yellow \(5{,}200\text{–}6{,}000\ \text{K}\) \(7.6\%\) Weak H, strong metals
K Orange \(3{,}700\text{–}5{,}200\ \text{K}\) \(12.1\%\) Very weak H, molecular bands
M Red-orange \(\lesssim 3{,}700\ \text{K}\) \(76.5\%\) TiO molecular bands

M dwarfs are \(76.5\%\) of all stars — too faint to see by eye.

Four Knobs, One Spectrum

What You Measure What It Tells You
Line positions (which wavelengths are dark) Composition — which elements are present
Line strength pattern (which species dominate) Temperature → spectral type (OBAFGKM)
Line widths (narrow vs. broad) Surface gravity / rotation → luminosity class
Metal line forest (amplitude relative to H) Metallicity (heavy-element abundance)

Temperature is the dominant knob — it controls line strengths so powerfully that it can mask composition differences entirely.

Why Temperature Controls Line Strength

  • For H absorption: electron must already be in \(n = 2\)
  • Fraction in \(n = 2\) depends on temperature: \(\propto e^{-\chi_2/k_BT}\)
  • Too cool (M stars): almost no atoms in \(n = 2\) → weak H lines
  • Just right (A stars): maximum population in \(n = 2\) → strongest H lines
  • Too hot (O stars): hydrogen is ionized → no neutral H → weak H lines

Predict First: Which Type Wins?

All stars are \({\sim}73\%\) hydrogen. Hydrogen Balmer absorption requires electrons already in \(n = 2\), which is \(10.2\ \text{eV}\) above the ground state.

At which spectral type — O, A, G, or M — would you expect the strongest Balmer lines, and why?

Commit to an answer before I show you.

The Goldilocks Problem: A Balmer Line Peak

Two competing effects at work:

  1. Excitation (\(\propto e^{-\chi_2/k_BT}\)): hotter → more atoms in \(n = 2\)
  2. Ionization: hotter → more atoms lose electrons entirely
Temperature Excitation Ionization Balmer strength
\(3{,}000\ \text{K}\) (M) Very low Negligible Weak — no \(n=2\)
\(10{,}000\ \text{K}\) (A) High Moderate Peak — sweet spot
\(35{,}000\ \text{K}\) (O) Very high Nearly complete Weak — no neutral H

Balmer strength rises, peaks at A stars, then falls — a competition, not monotonic growth.

Prediction: Why Weak H Lines?

An M star (\(T \approx 3{,}000\ \text{K}\)) has weak hydrogen Balmer lines.

Which explanation is correct?

  1. M stars have very little hydrogen

  2. M stars are too cool — almost no H atoms in the \(n = 2\) state

  3. M stars are so hot that hydrogen is ionized

  4. M stars are too far away to show lines

The Spectral Sequence Is Temperature

  • Do O stars have more helium? No — same composition. Temperature ionizes H and excites He.
  • Do A stars have more hydrogen? No — same abundance. Temperature puts H into \(n = 2\).
  • Do M stars lack hydrogen? No. Temperature keeps H atoms in \(n = 1\) (ground state).

Same atoms. Different temperatures. Different spectra.

🔍 Spectrum Detective — Clue 2: The pattern of line strengths tells you temperature (spectral type). Strong Balmer? \({\sim}10{,}000\ \text{K}\). TiO bands? Below \({\sim}3{,}700\ \text{K}\).

Quick Check: Spectral Type

Two stars have identical composition. Star X is spectral type A; Star Y is spectral type M. What’s different?

  • Star X has more hydrogen
  • Star Y has more metals
  • Star X is hotter, so more H atoms occupy the \(n = 2\) level
  • Star Y is closer, so lines appear weaker

Metallicity: A Secondary Effect

Metallicity (\(Z\)) = mass fraction of elements heavier than helium.

  • Sun: \(Z_\odot \approx 0.014\) — about \(1.4\%\) “metals”
  • High-\(Z\) stars: more and stronger metal absorption lines
  • Low-\(Z\) stars: “cleaner” spectra with fewer metal lines

But metallicity is second-order for classification. Two stars at the same temperature with different \(Z\) have the same spectral type — the metal line strengths differ, but which species dominates is set by temperature.

Beyond Temperature: What Line Widths Reveal

Artistic rendering of main-sequence stars arranged left to right by spectral type from M (small, red-orange) through K, G, F, A, B to O (large, blue-white), shown to relative scale against a black background. Each star is labeled with its spectral letter.
Credit: Wikimedia Commons (after Morgan & Keenan)
  • Giants/supergiants: low-density atmospheres → narrow spectral lines
  • Dwarfs (main-sequence): compact, dense atmospheres → broad spectral lines

G2V (Sun) and G2Ib (supergiant): same temperature, wildly different size and luminosity.

The Doppler Shift

Reading stellar motion from light

Doppler: Wavelength Shifts from Motion

Star with orbiting exoplanet showing how spectral lines shift: blueshifted when star moves toward viewer, neutral when perpendicular, redshifted when moving away. Three spectra shown for comparison.
Credit: JWST/STScI

Motion along the line of sight shifts all spectral lines:

  • Receding → lines shift to longer wavelengths (redshift)
  • Approaching → lines shift to shorter wavelengths (blueshift)

Typical stellar velocities: \(10\text{–}100\ \text{km/s}\) → shifts of only \({\sim}0.01\text{–}0.03\%\), but measurable.

The Doppler Formula

\[\frac{\Delta\lambda}{\lambda_0} = \frac{v_r}{c}\]

  • \(\Delta\lambda = \lambda_{\text{obs}} - \lambda_0\) — the shift
  • \(v_r\) — radial velocity (+ = receding, − = approaching)
  • \(c = 3.0 \times 10^5\ \text{km/s}\) — speed of light

Redshift (\(\Delta\lambda > 0\)): source receding | Blueshift (\(\Delta\lambda < 0\)): source approaching

Diagnostic: A real Doppler shift moves all lines by the same fraction \(\Delta\lambda/\lambda_0\). If only one line shifts — it’s a misidentification, not motion.

Worked Example: Radial Velocity from H\(\alpha\)

Problem: H\(\alpha\) observed at \(656.5\ \text{nm}\) (rest: \(656.3\ \text{nm}\)). Approaching or receding?

Step 1 — Direction: \(\lambda_{\text{obs}} > \lambda_0\)redshiftedreceding

Step 2 — Shift: \(\Delta\lambda = 656.5\ \text{nm} - 656.3\ \text{nm} = 0.2\ \text{nm}\)

Step 3 — Velocity: \[v_r = c \times \frac{\Delta\lambda}{\lambda_0} = (3.0 \times 10^5\ \text{km/s}) \times \frac{0.2\ \text{nm}}{656.3\ \text{nm}} \approx 91\ \text{km/s}\]

A \(0.03\%\) shift → \({\sim}91\ \text{km/s}\). Tiny shift, huge velocity.

Quick Check: Doppler Direction

H\(\beta\) (rest: \(486.1\ \text{nm}\)) is observed at \(485.9\ \text{nm}\). The star is…

  • Approaching (blueshifted — observed wavelength is shorter)
  • Receding (redshifted)
  • Stationary (no shift)
  • Rotating (broadened)

The Doppler Wobble in Action

Think–Pair–Share: Exoplanet Wobble

A star’s H\(\alpha\) line oscillates between \(656.25\ \text{nm}\) and \(656.35\ \text{nm}\) over a 4-day cycle. The rest wavelength is \(656.3\ \text{nm}\).

  1. Is the star moving? How do you know?
  2. What is the velocity amplitude (\(v_r\)) of the wobble?
  3. What could cause a periodic Doppler oscillation?

30 seconds alone → 1 minute with a neighbor → share out

Doppler Unlocks Masses

If a star is in a binary system, its radial velocity oscillates as it orbits.

Measure the oscillation period and amplitude → infer the companion’s mass.

Lecture 4: Binary orbits + Doppler → stellar masses.

🔍 Spectrum Detective — Clue 3: The shifts of line positions — every line offset by the same fraction — tell you the star’s radial velocity.

Putting It Together

Three clues from one spectrum

One Spectrum, Four Inferences

Observable What we measure What we infer
Line positions (which wavelengths are dark) Wavelengths matched to lab data Composition
Line strength pattern (which species dominate) Relative strengths Temperature → spectral type
Line shifts (offset from lab wavelengths) Doppler shift \(\Delta\lambda/\lambda_0\) Radial velocity
Line widths (narrow vs. broad) Pressure/rotational broadening Surface gravity → luminosity class

Composition, temperature, motion, and size — from a single observation.

🔍 Spectrum Detective — Case Closed. All clues collected: composition (Clue 1), temperature (Clue 2), velocity (Clue 3). Three independent measurements, one observation.

Multi-Clue Diagnosis

Observed: \(T \approx 9{,}500\ \text{K}\), strong Balmer lines, weak metals, H\(\alpha\) at \(656.1\ \text{nm}\)

(a) Spectral type: \({\sim}9{,}500\ \text{K}\) + strong Balmer → type A

(b) Velocity: \(\Delta\lambda = 656.1\ \text{nm} - 656.3\ \text{nm} = -0.2\ \text{nm}\) → blueshifted → approaching \[v_r = (3.0 \times 10^5\ \text{km/s}) \times \frac{-0.2\ \text{nm}}{656.3\ \text{nm}} \approx -91\ \text{km/s}\]

(c) What else do we need? Distance → luminosity → radius. Time-series Doppler → mass.

Try It Tonight: Read a Real Spectrum

Open the SDSS SkyServer Quick Look.

Enter: Plate 285, MJD 51930, Fiber 164 (a classic A star).

  1. Continuum shape — does it rise toward blue or red?
  2. Absorption lines — can you spot H\(\alpha\) (\(656\ \text{nm}\)) and H\(\beta\) (\(486\ \text{nm}\))?
  3. Line shifts — are lines at rest wavelengths, or offset?

You’ve just done real spectroscopy. Every line encodes the same physics from Parts 1–4.

The Module 2 Inference Chain

Lecture New Tool What It Unlocks
1 Parallax → distance Distance, then luminosity
2 Color → temperature; Stefan-Boltzmann Radius
3 Spectral lines Composition, refined \(T\), velocity
4 Binary orbits + Doppler Mass
5–6 Magnitudes + HR diagram Full classification

Five properties from photons alone. Mass needs one more tool.

Spectroscopy Meets Climate

Same physics, different scale

Planetary Energy Balance

At equilibrium: power absorbed from star = power radiated by planet.

\[T_{\text{eq}} = 279\ \text{K} \times (1-A)^{1/4} \times \left(\frac{d}{1\ \text{AU}}\right)^{-1/2}\]

For Earth (\(A = 0.3\), \(d = 1\ \text{AU}\)):

\[T_{\text{eq}} = 279\ \text{K} \times (0.70)^{1/4} \times 1 = 279\ \text{K} \times 0.915 = 255\ \text{K} = -18°\text{C}\]

Earth’s actual average: \(288\ \text{K} = +15°\text{C}\). Something warms us by \(33\ \text{K}\).

Predict First: What Warms Earth?

Earth’s equilibrium temperature is \(255\ \text{K}\) — well below freezing.

The observed average is \(288\ \text{K}\) — above freezing.

What must the atmosphere be doing to account for that \(33\ \text{K}\) difference?

Think about Kirchhoff’s third law applied to a planet instead of a star.

The Greenhouse Effect: Kirchhoff’s Law 3 for Planets

Diagram showing the electromagnetic spectrum with two Planck curves. Left panel (yellow background): incoming solar radiation peaking near 1 micron in the visible band. Right panel (blue background): outgoing terrestrial radiation peaking near 10 microns in the thermal infrared, with deep absorption notches carved by atmospheric greenhouse gases. The full EM spectrum from gamma rays to long waves is labeled across the top.
Credit: NOAA JetStream

Two Planck curves:

  1. Sun → Earth peaks at ~0.5 μm (visible) — passes through atmosphere
  2. Earth → space peaks at ~10 μm (IR) — blocked by greenhouse gases

CO\(_2\), H\(_2\)O, CH\(_4\) absorb outgoing IR and re-emit some back down → surface warms.

This IS Kirchhoff’s Law 3: atmosphere = “cool gas” absorbing from the “hot continuum” (Earth’s surface).

A Tale of Three Planets

Bar chart comparing equilibrium temperature (teal) and actual surface temperature (gold) for Venus, Earth, and Mars. Venus shows the largest greenhouse gap of +508 K, Earth shows +33 K, and Mars shows approximately zero. Dominant atmospheric greenhouse gases are labeled beneath each planet.
Credit: ASTR 201 (generated)
Planet \(T_{\text{eq}}\) (K) Actual \(T\) (K) Greenhouse warming
Venus \(227\) \(735\) \(+508\ \text{K}\)
Earth \(255\) \(288\) \(+33\ \text{K}\)
Mars \(210\) \(210\) \({\sim}0\ \text{K}\)

Same star, similar compositions. Atmosphere thickness makes all the difference.

CO\(_2\)’s 15 \(\mu\text{m}\) Band

Graph showing reflectance vs wavelength (400-2400 nm) for snow (high, flat), vegetation (red edge jump at 700 nm), dry soil (rising toward IR), and water (absorbs in IR). Each material has distinct spectral signature.
Credit: JWST/STScI

CO\(_2\) absorbs at 15 \(\mu\text{m}\) — right where Earth’s thermal radiation peaks.

Try It: Mars’s Equilibrium Temperature

Mars: \(d = 1.52\ \text{AU}\), \(A = 0.25\)

\[T_{\text{eq}} = 279\ \text{K} \times (1-0.25)^{1/4} \times \left(\frac{1.52\ \text{AU}}{1\ \text{AU}}\right)^{-1/2}\]

\((0.75)^{1/4} \approx 0.930 \qquad (1.52)^{-1/2} \approx 0.811\)

\[T_{\text{eq}} \approx 279\ \text{K} \times 0.930 \times 0.811 \approx 210\ \text{K}\]

Mars’s actual surface temperature is \({\sim}210\ \text{K}\). \(T_{\text{eq}} \approx T_{\text{surface}}\) — the greenhouse effect is negligible. Why? CO\(_2\) dominates (\(95\%\)), but the atmosphere is only \(0.6\%\) of Earth’s pressure. Too thin to trap significant IR.

Quick Check: Greenhouse Physics

The greenhouse effect warms Earth because…

  • CO\(_2\) absorbs incoming visible sunlight
  • The ozone layer traps heat
  • Atmospheric gases absorb outgoing infrared radiation and re-emit some downward
  • Earth’s core heats the surface

Two More Confusions to Clear Up

  • “Stronger lines = more of that element.” Not necessarily. Line strength depends primarily on temperature — which levels are populated — not abundance. An A star doesn’t have more hydrogen than an M star; it just has the right \(T\) to populate \(n = 2\).
  • “Absorption lines make a star dimmer.” Negligibly. Absorbed photons are re-emitted in random directions (resonant scattering). Total luminosity is conserved; the spectrum just has narrow dark features carved into it.

(Recall: we killed Myths 1 and 2 — spectral type ≠ composition, and redshift ≠ red star — at the start.)

What Spectra Can’t Tell Us (Directly)

  • Mass — need binary orbits + Doppler (Lecture 4)
  • Distance — need parallax or other distance indicator (Lecture 1)
  • Age — need stellar evolution models (Module 3)
  • Tangential velocity — Doppler gives only the radial component

Spectra are powerful — but not omnipotent. Every tool has limits.

Summary: Key Takeaways

  1. Kirchhoff’s laws connect spectral appearance to physical conditions — stars show absorption spectra because of their temperature gradient
  2. Spectral lines are atomic fingerprints — energy levels set wavelengths
  3. OBAFGKM is a temperature sequence — same composition, different excitation
  4. Doppler shift converts wavelength shifts to velocities — \(\Delta\lambda/\lambda_0 = v_r/c\)
  5. Greenhouse effect is Kirchhoff’s law 3 applied to planets — same physics, different scale

The Takeaway

If you forget everything else from today, remember this:

One spectrum → composition, temperature, velocity.

A star’s light is an autobiography — if you know how to read it.

Next Time: Binary Stars & Stellar Masses

Lecture 4: We put the Doppler shift to work on binary stars.

  • Radial velocity oscillations → orbital period + amplitude
  • Kepler’s laws → stellar masses
  • Mass is the property that determines a star’s entire life story

The last fundamental property — and the most important one.

Questions?

Common questions at this point:

  • “How do we know the lab wavelengths are right?” — Measured precisely since 1859
  • “Can we determine composition from just one line?” — Need multiple lines for confidence
  • “Do all stars have absorption spectra?” — Most, but emission-line stars exist (Be stars, Wolf-Rayet)